Isoprenylation of Polyphenols in Aqueous Acid Solutions
نویسنده
چکیده
Matract-Polyphenok condens with 2-methylbut-3cne-2-d or y,ydimethylallyl alcohol in 5% aqueous citric acid solution to yield phenolic 2Jdimethylchromans These facik condensation provide chemical support for the biogenetic theory of C-isopentenylation of phenols by 7,7dimcthylallyl pyrophosphate. Iso-psoralidin (20) has been synthesized from 7-hydroxy-2Jdimethylchroman (12) by a novel and convenient route.
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تاریخ انتشار 2001